Periods and Groups周期与族

Big Idea · Structure and Properties (SAP)AP Science Practice 1 · Models and RepresentationsAP link · Unit 1~30 min

Learning goals

  • Explain that the periodic table is arranged by atomic number, and read the atomic number, symbol, and atomic mass in each box
  • Describe the 7 periods and the 18 groups, and tell main-group elements from transition metals
  • Find the position of any of the first 20 elements from its atomic number, and find an element from its position

Before you start

  • Element symbols and names (1.4.1)
  • Atomic number and mass number (1.3.3)

A table that made predictions

In 1869, the Russian chemist Dmitri Mendeleev arranged the 60-some elements known at the time in order of atomic mass and noticed that elements with similar properties showed up again and again, at regular intervals. Boldly, he left gaps in his table, claimed they belonged to elements nobody had found yet, and predicted their properties. Within a few years, gallium and germanium were discovered, and they matched his predictions remarkably well. His table grew into today’s periodic table元素周期表.

How the table is arranged

Today’s periodic table holds 118 elements, arranged in order of atomic number. For an atom:

atomic number=nuclear charge=protons=electrons\text{atomic number} = \text{nuclear charge} = \text{protons} = \text{electrons}

Each box gives the element’s basic information. Here is iron:

WhereWhat it showsIron’s box
TopAtomic number26
MiddleElement symbolFe
Below the symbolName (on many tables)iron
BottomAtomic mass55.85

The atomic mass is the relative atomic mass from lesson 1.3.5. In calculations it’s usually rounded, so iron becomes 56.

Periods and groups

Rows: periods. The table has 7 rows, and each row is a period周期. The periods aren’t the same length: period 1 has only 2 elements, periods 2 and 3 have 8 each, periods 4 and 5 have 18 each, and periods 6 and 7 have 32 each.

Columns: groups. The table has 18 columns, numbered 1 to 18, and each column is a group族 (sometimes called a family). Elements in the same group have similar properties.

  • Groups 1, 2, and 13–18 hold the main-group elements.
  • Groups 3–12 hold the transition metals.
  • Several groups have family names: group 1 (except hydrogen) is the alkali metals, group 2 the alkaline earth metals, group 17 the halogens, and group 18 the noble gases.

To keep the table from getting too wide, two rows of 15 elements each, the lanthanides and actinides, are pulled out of periods 6 and 7 and printed underneath.

Older American textbooks label the main groups 1A–8A. Chinese textbooks use a similar system (ⅠA–ⅦA, then 0 for the noble gases) and count only 16 groups, because they treat columns 8, 9, and 10 as a single group.

Click any element to see its period and group. Then use the “Find it” game to locate elements from their positions:

Try it: click any element to see its period and group
Metals (92)Metalloids (6)Nonmetals (13)Noble gases (7)
s block: ns¹⁻²p block: ns²np¹⁻⁶d block (transition metals): (n−1)d¹⁻¹⁰ns⁰⁻²f block (inner transition metals)
Solid (90)Liquid (2)Gas (11)Unknown (15)

The table is wide: swipe sideways to see all of it.

123456789101112131415161718123456757–71Lanthanides89–103ActinidesLanthanidesActinides

Click any element in the table.

Example 1: From atomic number to position

Where is element 16 on the periodic table?

Step-by-step solution
  1. Find the period. Period 1 holds elements 1–2, period 2 holds 3–10, and period 3 holds 11–18. 16 falls in 11–18, so it’s in period 3.
  2. Find the group. Periods 2 and 3 have no transition metals, so group 2 is followed directly by group 13. Counting from element 11 (sodium, group 1): 12 is group 2, 13 is group 13, 14 is group 14, 15 is group 15, and 16 is group 16.
  3. Answer. Element 16 is sulfur (S), in period 3, group 16.

Example 2: Reading a box

Calcium’s box shows 20, Ca, calcium, and 40.08. What does each item tell you, and what else can you work out?

Step-by-step solution
  1. 20 is the atomic number. A calcium atom has 20 protons, a nuclear charge of +20, and 20 electrons.
  2. Ca and calcium are the symbol and name. Calcium is in group 2, so it’s an alkaline earth metal.
  3. 40.08 is the atomic mass. In calculations it’s usually rounded to 40.
  4. You can estimate the neutrons. The most common calcium atom has a mass number of about 40, so it has about 40 − 20 = 20 neutrons.
Practice: which period is each element in?
  1. Hydrogen (element 1)
  2. Oxygen (element 8)
  3. Sodium (element 11)
  4. Chlorine (element 17)
  5. Potassium (element 19)
  6. Neon (element 10)
  7. Helium (element 2)
  8. Calcium (element 20)
  9. Aluminum (element 13)

Common mistakes

Mistake 1: “Periods are columns and groups are rows.” It’s the other way around: periods run across (rows), and groups run down (columns).

Mistake 2: “The periodic table is arranged by atomic mass.” It’s arranged by atomic number. Mendeleev used atomic mass, so in a few places the two orders disagree: argon (39.95) comes before potassium (39.10).

Mistake 3: “Every period has 8 elements.” Only periods 2 and 3 do. Period 1 has 2, periods 4 and 5 have 18, and periods 6 and 7 have 32.

Quick check

Which element is in period 3, group 2?

Which statement about the periodic table is correct?

Summary

  • The periodic table is arranged by atomic number. Atomic number = nuclear charge = protons = electrons. Each box shows the atomic number, the symbol, and the atomic mass.
  • The 7 rows are periods; the 18 columns are groups 1–18. Groups 1, 2, and 13–18 are main groups; groups 3–12 are the transition metals.
  • Periods for the first 20 elements: 1–2 period 1, 3–10 period 2, 11–18 period 3, and 19–20 period 4.
On to AP (for later)

AP Chemistry uses the group numbers 1–18 from today’s lesson and expects you to know the family names: alkali metals (group 1), alkaline earth metals (group 2), halogens (group 17), and noble gases (group 18). Topics 1.7 and 1.8 use an element’s period and group to predict its properties and the charge on its ion.

Practice this chapter: Module 4 · The Periodic Table · 10 questions

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